Cover Picture: Bio‐adhesive Nanoporous Module: Toward Autonomous Gating (Angew. Chem. Int. Ed. 16/2021)

Spotlights on our sister journals: Angew. Chem. Int. Ed. 15/2018.

MAC it happen : Presented is a study of the synergistic structuredirecting effect of metal–amine complexes (MACs) with different chelating polyamine ligands and imidazolium-based ionic liquid (IL) cations. For the first time, a layered selenidostannate with an asymmetric eight-membered ring, an organic-decorated layered selenidostannate, and a 3D selenidostannate with both the MAC and IL cation...

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Encapsulated lanthanides as luminescent materials.

Angew. Chem. Int. Ed. 2002, 41, No. 14 1 WILEY-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002 1433-7851/02/4114-2495 $ 20.00+.50/

Semi - Empirical Study of a pH - Switchable [ 2 ] Rotaxane

Semi-empirical (AM1) electronic structure calculations are reported on a pH-switchable [2] rotaxane whose synthesis was reported in [Angew. Chem. Int. Ed., 36 (1997) 1904]. The [2] rotaxane possesses two cationic binding sites, with different affinities toward dibenzo [24] crown-8 (the ring component of the [2] rotaxane) depending upon the pH of the system. The computational results capture thi...

Crystal engineering of mixed-metal Ru-Ag coordination networks by using the trans-[RuCl2(pyz)4] (pyz = pyrazine) building block.

In the rational development of new strategies for the crystal engineering of coordination networks[1] and of metal-based supramolecular architectures[2] the use of predetermined building blocks has assumed an increasing relevance in recent times. For example, molecular corners containing transition metals with programmed coordination angles, such as cisprotected PdII and PtII square-planar comp...